Hydrogen occluding alloy and electrode made of the alloy

Chemistry: electrical current producing apparatus – product – and – Sealed cell having gas prevention or elimation means – Prevention or elimination means is one of the cell...

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429101, 429223, 4292182, 420900, H01M 438

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active

059323698

ABSTRACT:
This invention provides a hydrogen occluding alloy exhibiting high absorption/desorption rates, and excellent initial activation, the alloy having a composition comprising, by wt %, 25% to 45% of Zr, 1% to 12% of Ti, 10% to 20 % of Mn, 2% to 12% of V, 0.5% to 5% of at least one rare earth element, preferably comprising La and/or Ce, optionally 0.1% to 4% of Hf, and a balance being Ni (25% or more of Ni) and unavoidable impurities. The alloy has a structure comprising: a main phase made of a Zr--Ni--Mn based alloy, numerous cracks, and a regenerated phase made of rare earth element-Ni type alloy, the regenerated phase being exposed on the surfaces of the cracks, as well as electrodes made of the alloy.

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"Surface and metallographic microstructure of La-substituted AB.sub.2 compound (Ti,Zr) (Mn,Cr,Ni).sub.2 ", Intl. Symposium on Metal-Hydrogen Systems Fundamentals & Applns., Nov. 6-11, 1994, F.-J. Liu, G.Sandrock and S.Suda.
"Activation behaviour of ZrCrNiM.sub.0.05 metal hydride electrodes (M.ident.La, Mm (misch metal), Nd)", Journal of Alloys and Compounds, 185, (1992) (no month) Soo-Ryoung Kim and Jai-Young Lee, pp. L1-L4.
Journals of Alloys and Compounds, 231 (Dec. 1995) pp. 392-396, Surface and metallographic microstructure of the La-added AB.sub.2 compound (Ti, Zr) (Mn, Cr, Ni).sub.2, F.-J. Liu et al.

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