Hydrogen occluding alloy

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

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429 59, 429101, 429223, 204293, 420455, 420460, 420443, 420900, 148538, 148555, 148556, H01M 458

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active

059003340

ABSTRACT:
The present invention provides a hydrogen occluding alloy exhibiting high hydrogen absorption and desorption rates, and excellent initial activation in practical use, and a method of making it. There is provided a hydrogen occluding alloy having a composition comprising, by wt %, 32 to 38% of rare earth elements essentially consisting of La and/or Ce, 0.5 to 3.5% of Al, 0.5 to 10% of Mn, 0.005 to 0.5% of hydrogen, optionally 0.1 to 17% of Co, and the balance being Ni and unavoidable impurities; wherein the alloy has a microstructure characterized in that fine rare earth element hydride is dispersively distributed in a matrix having a CaCu.sub.5 -type crystal structure in a ratio of 0.5 to 20% by area. There are also provided electrodes and batteries containing such alloys, and methods of making and using such electrodes and batteries.

REFERENCES:
patent: 4222770 (1980-09-01), Osumi et al.
patent: 4663143 (1987-05-01), Wallace et al.
patent: 5470404 (1995-11-01), Yamamoto et al.
Chung et al. "A Study of Hydrogen-Induced Amorphization in the La-Ni System" of Journal of Non-Crystalline Solids 110(1989) 203-210, North-Holland Amsterdam No Month Available.
Fukumoto et al. "Hydrogen Absorption-Desorption Characteristics of Rare Earth Hydrogen storage Alloys with Nonstoichiometric Composition" presented at The 35th Battery Symposium in Japan on Nov. 14-16, 1994.
Wescon '94. Western Electronic Show and Convention, Anaheim, Sep. 27-29, 1994 Sep. 27, 1994, Institute of Electrical and Electronics Engineers, pp. 236-241, Dunbar J: "High Performance Nickel Metal Hydride Batteries".
Journal of Alloys and Compounds, vol. 231, No. 1, Dec. 15, 1995, pp. 392-396, (Liv et al.) Surface and Metallographic Microstructure of the La-Added AB2 Compound (Ti, Zr) (Mn, Cr, Ni).sub.2.

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