Hydrogen-generating reactors and methods

Gas: heating and illuminating – Generators – Portable

Reexamination Certificate

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C423S648100, C422S198000, C422S239000

Reexamination Certificate

active

07981171

ABSTRACT:
Reactors and methods that generate hydrogen from fuel, such as naturally-occurring or synthesized hydrocarbon fuel. One embodiment of the reactor comprises a CO2/H2active membrane piston disposed inside a cylinder that provides for highly efficient and scalable hydrogen generation from hydrocarbon fuels. This embodiment may function in a two or four stroke modes. Another embodiment of the reactor comprises a dual piston configuration having CO2and H2active membrane pistons inside a single cylinder. Other embodiments of the reactor comprise flexible membranes or diaphragms that operate in a manner similar to pistons with or without regeneration of residual reaction products. Exemplary methods introduce fuel into a controllable volume, selectively control pressure, temperature and residence time of the fuel within the controllable volume, chemically react the fuel within the controllable volume with one or more catalysts to produce one or more chemical species, selectively remove via a membrane one or more of the chemical species from the controllable volume, and exhaust residual products from the controllable volume.

REFERENCES:
patent: 6099621 (2000-08-01), Ho
patent: 2005/0023236 (2005-02-01), Adams et al.
patent: 2005/0074643 (2005-04-01), Adams et al.
patent: 2005/0158595 (2005-07-01), Marsh et al.
Huang, J., El-Azzami, L., Ho, W.S.W., (2005) “Modeling of CO2-selective water gas shift membrane reactor for fuel cell”, Journal of Membrane Science, 261 (1-2), 67-75.
Johannessen, E., Jordal, K., (2005) “Study of a H-2 separating membrane reactor for methane steam reforming at conditions relevant for power processes with CO2 capture”, Energy Conversion and Management, 46 (7-8), 1059-1071.
Barbieri, G., et al., (1997) “Methane steam reforming analysis in a palladium-based catalytic membrane reactor”, Industrial & Engineering Chemistry Research, 36 (8), 3369-3374.
Shu, J., et al., (1994) “Methane Steam Reforming in Asymmetric Pd-Ag and Pd-Ag/Porous Ss Membrane Reactors”, Applied Catalysis a-General, 119 (2), 305-325.

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