Hydrogen bronze catalyst for demetallizing petroleum resids

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502216, 502219, 502220, 502246, 502247, 502254, 502255, 502305, 502353, B01J 2320, B01J 2322, B01J 2328, B01J 2330

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active

049101811

ABSTRACT:
The catalyst composition comprises a layered metal oxide and/or sulfide of a metal selected from the group consisting of Group VB and VIB metals and containing inserted atomic hydrogen therein, with no chemical bond between said atomic hydrogen and anionic oxygen or anionic sulfur of the oxide or sulfide. It is useful for demetallizing resids.

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"Mat. Res. Bull.", vol. 14, pp. 369-376 Ionic Bonding Model of the Pyridine Intercalation Compounds of Layered Transition Metal Dichalcogenides.
"Angew, Chem. Int. Ed. Engl.", 19, 983-1003 (1980) Reversible Topotactic Redox Reactions of Solids by Electron/Ion Transfer.
"Intercalation Chemistry" pp. 315-360, pp. 315-360 Solvated Intercalation Compounds of Layered Chalcogenide and Oxide Bronzes.
New Catalytic Materials: vol. VII Layered Structured as Novel Catalysts "Ind. Eng. Chem. Process Des. Dev.", vol. 16, No. 4, 1977, pp. 525-528.
Fresh Water Manganese Nodules as a Catalyst for Demetalizing and Desulfurizing Petroleum Residua.
The Shaker Bomb, John W. Payne, Carl W. Streed and Eric R. Kent, R&D Lab., Socony Mobil Oil Co. Inc., Paulsboro, NJ.

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