Hydrogen and carbon dioxide coproduction apparatus

Chemical apparatus and process disinfecting – deodorizing – preser – Chemical reactor – With means applying electromagnetic wave energy or...

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481279, 422190, 422234, B01J 700

Patent

active

050009257

ABSTRACT:
Highly purified gaseous hydrogen and liquid carbon dioxide are produced from a steam reformer/shift converter by passing the effluent from the latter through a multibed hydrogen PSA unit followed by an uncoupled carbon dioxide PSA unit. The carbon dioxide PSA unit produces a hydrogen-rich stream which is recycled to the feed to the steam reformer, a carbon dioxide-rich recycle stream which is recycled to the carbon dioxide PSA unit feed and a carbon dioxide-rich product stream which is introduced under pressure to a liquifier. A waste stream from the liquifier is recycled to the carbon dioxide PSA unit feed. A portion of the carbon dioxide-rich product stream is withdrawn from the compressor at a stage such that its pressure is higher than that of the carbon dioxide PSA unit and returned thereto as a cocurrent purge preceding bed regeneration to obtain product.

REFERENCES:
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Kirk-Othmer, Encyclopedia of Chem Tech., 3rd ed., vol. 4, Johm Wiley & Sons, (1978) pp. 725, 737, 738.

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