Hydrogen-absorbing alloy for a negative electrode and manufactur

Chemistry: electrical current producing apparatus – product – and – Sealed cell having gas prevention or elimation means – Prevention or elimination means is one of the cell...

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429101, 429218, 420900, H01M 404

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active

053764749

ABSTRACT:
The disclosure relates to a hydrogen-absorbing alloy for a negative electrode comprising: a main texture of Mm-Ni system having a crystal structure of CaCu.sub.5 type; and a plurality of compound phases having a crystal structure other than the crystal structure of CaCu.sub.5 type, where each of the compound phases are segregated in the main texture, and wherein a volume of each of the compound phases is less than about 10 .mu.m.sup.3. A distance between two adjacent compound phases should be less than about 100 .mu.m. In the hydrogen-absorbing alloy the compound phases should include an element selected from a group of boron (B), carbon (C), tantalum (Ta), niobium (Nb), titanium (Ti), zirconium (Zr), molybdenum (Mo), tungsten (W) and bismuth (Bi).

REFERENCES:
patent: 3824131 (1974-07-01), Beccu
patent: 4487817 (1984-12-01), Willems et al.
patent: 4623597 (1986-11-01), Sapru et al.
patent: 4925748 (1990-05-01), Ikoma et al.
patent: 5071720 (1991-12-01), Notten
patent: 5135589 (1992-08-01), Fetcenko et al.
"Double-Phase Hydride Forming Compounds: A New Class of Highly Electrocatalytic Materials", Notten and Hokkeling, J. Electrochem. Soc., vol. 138, No. 7, Jul. 1991, pp. 1877-1887.

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