Hydroformylation process using stable rhodium catalyst

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 4550

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042835623

ABSTRACT:
In a rhodium-catalyzed hydroformylation process which produces aldehydes from olefins, the stability of a rhodium catalyst complexed with carbon monoxide and a phosphine ligand is improved by the use of a ligand selected from a branched chain alkyldiphenylphosphine, a branched chain dialkylphenylphosphine, a cycloalkyldiphenylphosphine and a dicycloalkylphenylphosphine.

REFERENCES:
patent: 3527809 (1970-09-01), Pruett et al.
patent: 3644446 (1972-02-01), Booth et al.
patent: 4151209 (1979-04-01), Paul et al.
Falbe, "Carbon Monoxide in Organic Synthesis", pp. 18-22, (1970), Spring-Verlag, N.Y.

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