Hydroformylation process and bisphosphite compound used therein

Details Hydroformylation process and bisphosphite compound used therein Hydroformylation process and bisphosphite compound used therein

1993-04-16

1995-02-21

Richter, Johann

Organic compounds -- part of the class 532-570 series

Organic compounds

Phosphorus esters

558160, C07F 0906

Patent

active

053918010

ABSTRACT:
A hydroformylation process for preparing a hydroformylated product by reacting an olefinic compound with hydrogen and carbon monoxide in the presence of a Group VIII metal catalyst, in the reaction of which there is present a phosphite compound having the formula (I), ##STR1## wherein R.sup.1 and R.sup.2 are respectively an aromatic hydrocarbon groups which may be the same or different and the aromatic hydrocarbon group has at least a hydrocarbon group on a carbon atom adjacent to a carbon atom bonded with an oxygen atom as a substituent; A.sup.1 is an n-valent organic group having an aliphatic hydrocarbon group, a cycloaliphatic hydrocarbon group or an aromatic hydrocarbon group bonded with an adjacent oxygen atom, which may respectively have a substituent; n is an integer of from 2 to 4; and the respective [--O--P(OR.sup.1)(OR.sup.2)] group may be the same or different.

REFERENCES:
Billig et al, Chem. Abstracts vol. 107, 7392r, "Bis(phosphite) complexes as hydroformylation catalyst precursors," (1987).

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