Hydroformylation of dicyclopentadiene to its dimethanolic deriva

Details Hydroformylation of dicyclopentadiene to its dimethanolic deriva Hydroformylation of dicyclopentadiene to its dimethanolic deriva

1979-03-16

1981-04-14

Helfin, Bernard

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568909, C07C 2916

Patent

active

042621470

ABSTRACT:
Dicyclopentadiene is selectively and substantially hydroformylated to its dimethanolic derivatives by a process comprising contacting dicyclopentadiene with a gaseous mixture of carbon monoxide and hydrogen at a temperature of at least about 100.degree. C. and a pressure of at least about 1,000 psig in the presence of a catalytic amount of a catalyst consisting essentially of a rhodium-cobalt bimetallic cluster, such as Rh.sub.2 Co.sub.2 CO.sub.12, supported on an amine resin, such as DOWEX.RTM. MWA-1.

REFERENCES:
patent: 2841614 (1958-07-01), Buchner et al.
patent: 2850536 (1958-09-01), Buchner et al.
patent: 2875244 (1959-02-01), Bartlett et al.
patent: 2880241 (1959-03-01), Hughes
patent: 2881208 (1959-04-01), Buchner et al.
patent: 4144191 (1979-03-01), Hartwell et al.

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