Hydroformylation catalyst and process

Details Hydroformylation catalyst and process Hydroformylation catalyst and process

1984-04-11

1985-09-17

Garvin, Patrick P.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

502154, 502155, 502162, 568454, B01J 2708, B01J 2710, B01J 3124

Patent

active

045421200

ABSTRACT:
Olefins are hydroformylated with syngas in the presence of a novel organo metallic complex catalyst to form the corresponding aldehydes at high reaction rates and improved selectivity of linear aldehydes over branched aldehydes.
The novel catalyst comprises an organo metallic complex formed from a mixture of:

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patent: 3981925 (1976-09-01), Schwager et al.
patent: 3996293 (1976-12-01), Knifton et al.
patent: 4101565 (1978-07-01), Poist
patent: 4155939 (1979-05-01), Poist
patent: 4256616 (1981-03-01), Hatanaka
patent: 4370258 (1983-01-01), Ogata et al.
patent: 4405496 (1983-09-01), Hsu
Kirk-Othmer, Encyclopedia of Chemical Technology, (third edition), vol. 16, pub. by John Wiley & Sons, N.Y., N.Y., pp. 637-653.
J.A.C.S., 97, 3553, (1975).
J. of Cat., 45, pp. 256-267, (1976).
J.C.S.-Chem. Comm., pp. 462-463, (1979).

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