Hydrodesulfurization of hydrocarbons with fluorided platinum

Mineral oils: processes and products – Refining – Sulfur removal

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208208R, C10G 4510

Patent

active

043929460

ABSTRACT:
A process for the desulfurization of a hydrocarbon fraction having unsaturated hydrocarbons and sulfur compounds comprising the steps of contacting the hydrocarbon fraction with hydrogen gas and a fluorided platinum catalyst in the presence of an oxygen-containing hydrogenation moderator which is either water or an oxygen-containing material which is hydrogenatable to water and whose hydrogenation products will not poison the platinum catalyst. The oxygen-containing hydrogenation moderator should be present in sufficient quantity to substantially prevent the saturation of the unsaturated hydrocarbons without seriously affecting the desulfurization of the hydrocarbon fraction. A preferred oxygen-containing hydrogenation moderator is carbon monoxide.

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