Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And group viii containing
Patent
1984-05-18
1985-07-23
Dees, Carl F.
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
And group viii containing
502210, 502211, B01J 2906, B01J 2718
Patent
active
045309116
ABSTRACT:
A method is disclosed for preparing a supported hydrogenation metal catalyst containing one each of Mo or W and of Co and/or Ni incorporated into a suitable support. An aqueous impregnating solution containing the desired quantity of catalytically active metals and having a pH in the range of about 0.7-2.7 is prepared containing (1) at least one each of a soluble compound of molybdenum or tungsten and a compound of cobalt and/or nickel; (2) a solubilizing amount of about 0.2-1.0 mole of phosphorous per mole Mo or W; and (3) about 2-6% w basis support, of a suitable soluble amine compound, such as amine alcohols, polyamines and amine acids. A suitable support, e.g., alumina, silica or silica-alumina, is then impregnated with the metals-containing solution. After impregnation the support is dried and calcined. This preparation method significantly increases the hydrodenitrification activity of the resulting catalyst in a hydrocarbon hydroconversion process.
REFERENCES:
patent: 3629146 (1971-12-01), Adams
patent: 3965041 (1976-06-01), van Klinken et al.
patent: 4407726 (1983-10-01), Rizkalla
patent: 4444906 (1984-04-01), Callahan et al.
patent: 4446248 (1984-05-01), Simpson et al.
Adams Charles T.
Ryan Robert C.
Washecheck Don M.
Dees Carl F.
Shell Oil Company
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