Hydrodenitrification catalyst

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Sulfur or compound containing same

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502 74, 502 87, 502150, 502174, 502220, 208254H, B01J 2702, B01J 2906, B01J 3102, B01J 2720

Patent

active

045489203

ABSTRACT:
A method for preparing hydrotreating catalysts containing Group VIII and/or Group VIB catalytically active metals on a support, and particularly those containing nickel and molybdenum, are improved in hydrodenitrification (HDN) activity by incorporating zero-valence molybdenum and/or tungsten carbonyls into the catalyst support by mixing a liquid mixture containing metal carbonyl(s); a catalytic amount of dienes, trienes or monoaromatics; and free sulfur; with a dried catalyst support and heating the liquid-solid mixture until metal carbonyl conversion to metal disulfide is substantially complete. The catalyst is then dried followed by calcining in inert gas, before use in a hydrotreating process.

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