Hydrodehalogenation process and catalyst for use therein

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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585642, 502325, C07C 126

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active

054302145

ABSTRACT:
A hydrodehalogenation process, comprising the step of reacting a saturated halohydrocarbon (e.g., 1,2-dichloropropane) with hydrogen or a hydrogen donor in the gas phase in the presence of a catalytically effective amount of ruthenium on a support, and at temperatures of at least about 100 degrees Celsius, to produce reaction products including a corresponding non-halogenated, unsaturated hydrocarbon (e.g., propylene).

REFERENCES:
patent: 2379697 (1945-07-01), Evans et al.
patent: 3892818 (1975-07-01), Scharfe et al.
patent: 4818368 (1989-04-01), Kalnes et al.
patent: 4899001 (1990-02-01), Kalnes et al.
patent: 5013424 (1991-05-01), James, Jr. et al.

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