Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing
Patent
1986-08-22
1988-06-07
Evans, J. E.
Organic compounds -- part of the class 532-570 series
Organic compounds
Halogen containing
C07C 1724, C07C 1700
Patent
active
047498170
ABSTRACT:
Polychlorobenzenes are selectively dechlorinated to dichlorobenzenes and monochlorobenzene in the vapor phase in the presence of a sulfided palladium or platinum catalyst. The reaction may be carried out at a temperature of from 225.degree. C. to 450.degree. C., preferably at atmospheric pressure, with an equimolar ratio of hydrogen and polychlorobenzene, and a space velocity of 0.5 to 5 wt. feed/wt. catalyst-hour. Only small amounts of benzene are formed.
REFERENCES:
patent: 2866828 (1958-12-01), Crowder
patent: 2949491 (1960-08-01), Rucker
patent: 3336386 (1967-08-01), Dovell et al.
patent: 3595931 (1971-07-01), Hay et al.
patent: 3892818 (1975-07-01), Scharfe et al.
Del Prato Thomas A.
George Jacob
Stufano Nicola A.
Evans J. E.
Lewen Bert J.
Standard Chlorine of Delaware Inc.
Sternberg Henry
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