Hydrodechlorination of chlorinated benzenes

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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C07C 1724, C07C 1700

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047498170

ABSTRACT:
Polychlorobenzenes are selectively dechlorinated to dichlorobenzenes and monochlorobenzene in the vapor phase in the presence of a sulfided palladium or platinum catalyst. The reaction may be carried out at a temperature of from 225.degree. C. to 450.degree. C., preferably at atmospheric pressure, with an equimolar ratio of hydrogen and polychlorobenzene, and a space velocity of 0.5 to 5 wt. feed/wt. catalyst-hour. Only small amounts of benzene are formed.

REFERENCES:
patent: 2866828 (1958-12-01), Crowder
patent: 2949491 (1960-08-01), Rucker
patent: 3336386 (1967-08-01), Dovell et al.
patent: 3595931 (1971-07-01), Hay et al.
patent: 3892818 (1975-07-01), Scharfe et al.

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