Hydrocracking using solid superacid catalysts comprising platinu

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking

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208112, 585653, C10G 4714

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active

054945690

ABSTRACT:
A hydrocracking process is provided which process utilizes a sulfated solid catalyst comprising (1) oxide or hydroxide of Group III or Group IV element, e.g. zirconium, and (2) a first metal comprising a metal or combination of metals selected from the group consisting of platinum, palladium, nickel, platinum and rhenium, and platinum and tin. The catalyst may further comprise (3) a second metal selected from the group consisting of Group VIII elements, e.g. iron. One embodiment of the invention further comprises (4) a third metal selected from the group consisting of Group V, VI and VII elements, e.g. manganese.

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Hino et al., "Synthesis of Solid Superacid Catalyst with Acid Strength of H.sub.o .ltoreq.-16.04", J.C.S. Chem. Comm., (1980), pp. 851-852.
Hosoi et al., "Characterization and C.sub.5 /C.sub.6 Isomerization Activity of Solid Superacid (Pt./SO.sub.4.sup.2- /ZrO.sub.2)" Amer. Chem. Soc. Los Angeles Meeting, Sep. 1988, Div. Petr. Chem. Pre. Print, 562-567.

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