Hydrocracking of feedstocks and catalyst therefor

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And additional al or si containing component

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502 71, 502 74, B01J 2910, B01J 2930

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active

053842979

ABSTRACT:
A tri-elemental catalyst on a support that includes a pentasil crystalline zeolite and is suitable for hydrocracking and hydrogenation of aromatics-containing petroleum hydrocarbon feedstocks such as hydrotreated cracked feedstock, virgin feedstock, vacuum distillate, middle distillate, mixtures thereof, and the like, is disclosed. The catalyst is suitable for hydrodesulfurization as well as hydrodenitrogenation, thus the feedstock can contain sulfur and nitrogen in addition to the aromatic components. Hydrocracking and aromatics hydrogenation of the petroleum hydrocarbon feedstocks is accomplished under a relatively wide range of process conditions in plural process zones using the tri-elemental catalyst that contains a catalytically active metal phase constituted by a Group VI-B element, a Group VIII first transition series element and a Group VIII second transition series element. In an upstream zone the catalytically active metal phase is supported on a titania-alumina support containing about 5% to about 30% by weight titania in the support. In a downstream zone the catalytically active metal phase is supported on a titania-alumina-pentasil crystalline zeolite support. The preferred pentasil crystalline zeolite is ZSM-5.

REFERENCES:
patent: 4120825 (1978-10-01), Ward
patent: 4740487 (1988-04-01), Matheson et al.
patent: 4816538 (1989-03-01), Abdo
patent: 5071805 (1991-12-01), Winslow et al.
patent: 5168085 (1992-12-01), Addiego et al.

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