Hydrocracking in strong acid systems with noble metal component

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking

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208111, 208112, 252441, 252477R, 260667, C10G 1308

Patent

active

040367371

ABSTRACT:
Hydrocarbon feedstocks are hydrocracked by contacting the feedstock in the presence of hydrogen and under hydrocracking reaction conditions with a catalyst comprised of a metal fluoride, the metal being boron, tantalum, niobium or mixtures thereof, a fluoride containing Bronsted acid and a Group VIII noble metal hydrogenation component, the Bronsted acid being present in at least an equi-molar amount relative to the metal fluoride and sufficient to dissolve at least a portion of the metal fluoride. The presence of the noble metal hydrogenation component serves to extend the hydrocracking catalyst life of the metal fluoride and fluoride containing Bronsted acid. The catalyst can be described as a slurry or dispersion composed of a solid noble metal on a support in a liquid phase acid system.

REFERENCES:
patent: 2446998 (1948-08-01), Burk
patent: 3409684 (1968-11-01), Aristoff et al.
patent: 3847795 (1974-11-01), Rieve et al.

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