Hydroconversion processes employing multi-metallic catalysts...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Sulfur or compound containing same

Reexamination Certificate

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C502S152000, C502S168000, C502S170000, C502S208000, C502S209000, C502S210000, C502S211000, C502S213000, C502S219000, C502S220000, C502S221000, C502S222000, C502S223000

Reexamination Certificate

active

07816298

ABSTRACT:
A catalyst precursor composition and methods for making such catalyst precursor is disclosed. The catalyst precursor comprises at least one of a Group IIB metal compound, a Group IVA metal compound, a Group IIA metal compound, and combinations thereof, at least one Group VIB metal, at least one organic, oxygen-containing ligand, and optionally a cellulose-containing material. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds. In one embodiment, the catalyst precursor is of the formula Av[(MP) (OH)x(L)ny]z(MVIBO4), wherein A comprises an alkali metal cation, an ammonium, an organic ammonium or a phosphonium cation, MPis selected from Group IIB, Group IVA and combinations thereof, having an oxidation state of either +2 or +4; L is at least one organic, oxygen-containing ligand, MVIBis at least one a Group VIB metal having an oxidation state of +6, MP:MVIBhas an atomic ratio of 100:1 to 1:100; v−2+P*z−x*z+n*y*z=0; and 0≦y≦−P
; 0≦x≦P; 0≦v≦2; 0≦z.

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