Hydroconversion process employing catalyst with specified pore s

Mineral oils: processes and products – Refining – Sulfur removal

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Details

208112, 208217, 208251H, C01G 4504, C01G 4712

Patent

active

053992598

ABSTRACT:
Heavy oils may be hydrotreated in the presence of a porous alumina support bearing metals of Group VIII and VI-B and optionally phosphorus, the catalyst having a Total Surface Area of 165-230 m.sup.2 /g, a Total Pore Volume of 0.5-0.8 cc.g, and a Pore Diameter Distribution whereby less than about 5% of the Total Pore Volume is present as primary micropores of diameter less than 80.ANG., and secondary micropores of diameter of .+-.20.ANG. of a Pore Mode of 100-135.ANG. are present in amount of at least about 65% of the micropore volume having pores with diameter less than 250.ANG., and 22-29% of the Total Pore Volume is present as macropores of diameter >250.ANG.. The process of the instant invention is particularly effective in achieving desired levels of hydrodemetallation, hydrodesulfurization, and hydrocracking of asphaltenes in the fraction of hydrotreated/hydrocracked petroleum resid product having a boiling point greater than 1000.degree. F.

REFERENCES:
patent: 4941964 (1990-07-01), Dai et al.

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