Hydrocarbonylation over iron on support having silica alumina di

Details Hydrocarbonylation over iron on support having silica alumina di Hydrocarbonylation over iron on support having silica alumina di

1976-02-13

1977-04-19

Helfin, Bernard

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260604HF, 252459, C07C 4504

Patent

active

040188345

ABSTRACT:
A separate phase of alumina is the matrix in which a separately prepared silica alumina is dispersed in the mixture of aqueous gels, which mixture is spray dried, and the solids calcined at about 1350.degree. F for about 3 hours. From about 0.001% to about 0.1% iron is impregnated into the support. Hydrocarbonylation of pentene-1 over such iron-containing catalyst provides hexanol and hexanal with an attractive combination of activity, selectivity, and stability for the catalytic process, the iron remaining on the support after repeated leaching by liquid product.

REFERENCES:
patent: 2497303 (1950-02-01), Gresham
patent: 3352924 (1967-11-01), Gladrow

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