Hydrocarbonylation

Details Hydrocarbonylation Hydrocarbonylation

1978-07-19

1984-11-13

Helfin, Bernard

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568429, 568444, 564305, 260598, 260599, 260578, 260584A, 260602, 260600, C07C 4550

Patent

active

044827482

ABSTRACT:
The homogeneous catalysis of the hydrocarbonylation of olefins using a catalyst comprising a complex between an organic ligand and a Group VIII noble metal hydride carbonyl. The reaction is performed at mild conditions including temperatures from 50.degree.-200.degree. C. and pressures from 1 to 10,000 atmospheres to produce a predominantly aldehyde product having a high normal to iso distribution. The aldehyde products so produced are useful as intermediates for hydrogenation to aliphatic alcohols, for aldol condensation to produce plasticizers, for oxidation to produce aliphatic acids, etc.

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