Hydrocarbon upgrading process

Mineral oils: processes and products – Chemical conversion of hydrocarbons – With subsequent treatment of products

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208 95, 208 62, 208134, 208135, G10G 6908

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058659889

ABSTRACT:
Low sulfur gasoline is produced from an olefinic, cracked, sulfur-containing naphtha by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5 to crack low octane paraffins and olefins under relatively mild conditions, with limited aromatization of olefins and naphthenes. This is followed by hydrodesulfurization over a hydrotreating catalyst such as CoMo on alumina. The initial treatment over the acidic catalyst removes the olefins which would otherwise be saturated in the hydrodesulfurization, consuming hydrogen and lowering product octane, and converts them to compounds which make a positive contribution to octane. Overall liquid yield is high, typically at least 90 percent of higher. Product aromatics are typically increased by no more than 25 weight percent relative to the feed and may be lower than the feed.

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