Hydrocarbon synthesis from lower alkanes at advanced temperature

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By isomerization

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585400, 585500, 585700, 585743, 585671, 585943, C07C 200, C07C 202, C07C 254

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050736663

ABSTRACT:
Upon a pressure vessel reactor, lower alkanes such as methane and propane subjected to temperatures of up to 800 K and pressures up to 70,000 psi (467 MPa), isomerize even in the absence of catalyst to produce a variety of alkanes, alkenes, cycloalkanes and aromatic hydrocarbons containing up to twelve carbon atoms.

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Journal of Catalysis, vol. 73, "Synthesis of Ethylen via Oxidative Coupling of Methane," Keller and Bhasin, pp. 9-19 (1982).
NTIS Report No. SAND-88-7092C by David Gray et al., May 20, 1988.
Gold, Thomas et al., Geochimiia et Cosmechimica Acta vol. 50, pp. 2411-2418 (1986).

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