Hydrocarbon soluble magnesium compositions of high magnesium con

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07F 302

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042229693

ABSTRACT:
A composition of matter comprising di-n-butylmagnesium and dimethylmagnesium, to the exclusion of dialkylmagnesium compounds containing alkyl groups other than n-butyl or methyl, with an n-butyl:methyl alkyl group ratio of about 0.2:1 to about 5:1 which is soluble in aliphatic, cycloaliphatic, and aromatic hydrocarbon solvents is disclosed. The composition is prepared in the substantial absence of oxygen and moisture by the simultaneous or consecutive reactions of methyl and n-butyl halides with metallic magnesium in the presence of the hydrocarbon solvent, followed by separation of the insoluble magnesium chloride and any unreacted magnesium metal from the resulting solution.

REFERENCES:
patent: 3264360 (1966-08-01), Nudenberg et al.
patent: 3450683 (1969-06-01), Hsich et al.
patent: 3646231 (1972-02-01), Kamienski et al.
patent: 3704287 (1972-11-01), Johnson
patent: 3737393 (1973-06-01), de Vries
patent: 3766280 (1973-10-01), Kamienski et al.
patent: 4069267 (1978-01-01), Kamienski et al.
patent: 4127507 (1978-11-01), Fannin et al.
Chemical Abstracts 88, 170793v, (1978).
Chemical Abstracts 88, 170794w (1978).

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