Chemistry of inorganic compounds – Nitrogen or compound thereof – Hydrogen containing
Patent
1976-06-04
1978-05-23
Garvin, Patrick P.
Chemistry of inorganic compounds
Nitrogen or compound thereof
Hydrogen containing
252429A, 252429B, 252438, 423472, 423644, 526159, 526161, 526164, 526169, C01B 2100, B01J 3100, B01J 2724, C01B 1100
Patent
active
040910822
ABSTRACT:
Hydrocarbon-soluble compositions useful as the transition metal component in the Ziegler polymerization of .alpha.-olefins are provided by reacting molecular nitrogen or hydrogen with a transition metal compound such as titanium trichloride to form a dinitrogen or dihydrogen complex of the transition metal compound.
REFERENCES:
patent: 1491588 (1924-04-01), Duparc et al.
patent: 3403197 (1968-09-01), Seelbach et al.
Dinitrogen Complexer of Osmium (III) and Ruthenium (III) Ammines Chemical Communications, 1970 pp. 875-876 Elson et al.
The Interaction of Dinitrogen Complexer of Ruthenium and Osmium with metal salts. Chemical Communications, 1970, pp. 90-91, Chatt et al.
Bioinorganic Chemistry, Advances in Chemistry Series 100, 79 (1971), Allen. pp. 79-94.
Bioinorganic Chemistry, Advances in Chemistry Series 100, 95 (1971), "Fixation of Molecular Nitrogen Under Mild Cond. pp. 95-110.
Chemical Reviews, 73 11(1973) Allen et al. pp. 11-20.
Gessell Donald Earl
Lowery, Jr. Kirby
Carter J. G.
Garvin Patrick P.
Jenkins M.S.
The Dow Chemical Company
Wright William G.
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