Hydrocarbon processing using fullerene catalysts

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By dehydrogenation

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585658, C07C 5327

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053368282

ABSTRACT:
A process is described for carrying out the dehydrogenation or hydrogenation, including hydrogenolysis, of a hydrocarbon in the presence of one or more soluble fullerene catalysts which have been dissolved in the hydrocarbon (when the hydrocarbon is a liquid capable of dissolving the fullerene catalyst) or dissolved in a solvent which is also a solvent for the hydrocarbon (when the hydrocarbon either is not a liquid or is not a liquid which is a solvent for the fullerene catalyst). The use of a liquid catalyst, i.e., a dissolved fullerene catalyst, inhibits coking reactions to thereby inhibit formation of coke on a solid catalyst or catalyst support by elimination of nucleation points or growth regions for such coke formation.

REFERENCES:
Bae, Y. K., et al., "Production, Characterization, and Deposition of Carbon Clusters", Symposium on Clusters and Cluster Assembled Materials: Special Session on Buckminsterfullerene, Boston, Mass., Nov. 29, 1990, published in The Proceedings of the 1990 Meeting of the MRS Society, pp. 1-9.
Kratschmer, W., et al., "Solid C.sub.60 : A New Form of Carbon" Nature, vol. 347, Sep. 27, 1990, pp. 354-357.

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