Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1987-01-02
1990-01-23
Lone, Werren B.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260413, 560241, 5602411, 5625122, 562549, 5683988, 568399, 568910, 5689105, C07C 6700, C07C 2712, C07C 4532
Patent
active
048956821
ABSTRACT:
Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidixed with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively in high yields when there is employed as the catalyst a highly active azide-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is azide. The invention is also directed to certain novel azide-activated metal coordination complex catalysts per se.
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J. E. Lyons, Hydrocarbon Processing, Nov. 1980, p. 107, Table I.
Taylor et al., J. Chem. Soc. Chem. Comm., 279 (1984).
Mansuy et al., ibid., 253 (1983).
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Tabushi et al., ibid., 103, 7371 (1981).
Ellis, Jr. Paul E.
Lyons James E.
Myers, Jr. Harry K.
Hess J. Edward
Johnson Donald R.
Lone Werren B.
Sun Refining and Marketing Copany
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