Hydrocarbon oxidations catalyzed by azide-activated metal coordi

Details Hydrocarbon oxidations catalyzed by azide-activated metal coordi Hydrocarbon oxidations catalyzed by azide-activated metal coordi

1990-01-17

1992-03-03

Shah, Mukund J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

540140, C07D48722

Patent

active

050934910

ABSTRACT:
Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively on high yields when there is employed as the catalyst a highly active azide-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is azide. The invention is also directed to certain novel azide-activated metal coordination complex catalysts per se.

REFERENCES:
Kennedy et al, Inorg. Chem. 1986, 25(15), 2539-45, Chemical Abstracts, vol. 105, 1986, Abstract 34539j.
Hill et al., JACS, 1980, 102, 6374-6377.
Tabushi et al, JACS, 1981, 103, 7371-7373.
Smegal et al, JACS, 1983, 105, 3515-3521.
Mansuy et al., J. Chem. Soc. Chem. Communications 6: 1983, pp. 253-254.
Hanack et al., Synth. Methods, 1987, 19(1-3), 787-92, Chemical Abs., vol. 107, 1987, Abstract 69540.

Affiliated with

Also associated with

Rating

Hydrocarbon oxidations catalyzed by azide-activated metal coordi does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Hydrocarbon oxidations catalyzed by azide-activated metal coordi, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hydrocarbon oxidations catalyzed by azide-activated metal coordi will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-273472