Hydrocarbon dehydrogenation with an attenuated superactive multi

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – From alicyclic

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585440, 585444, 585660, C07C 541, C07C 402

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active

043130208

ABSTRACT:
Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at hydrocarbon dehydrogenation conditions, with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component maintained in the elemental metallic state, and of a germanium component. An example of the attenuated superactive nonacidic multimetallic catalytic composite disclosed herein is a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of an alkali or alkaline earth component, a germanium component, and of a platinum group component which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component.

REFERENCES:
patent: 2620314 (1952-12-01), Hoekstra
patent: 2892858 (1959-06-01), Ziegler
patent: 3661805 (1972-05-01), Horvath
patent: 3723557 (1973-03-01), Hayes
patent: 3852190 (1974-12-01), Buss et al.
patent: 4012313 (1977-03-01), Buss et al.
patent: 4104317 (1978-08-01), Antos
patent: 4165276 (1979-08-01), Antos

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