Hydrocarbon conversion with ZSM-22 zeolite

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585475, 585486, C07C 527, C07C 266

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active

052488411

ABSTRACT:
Alkylated aromatic compounds, either alone or in a mixture with an alkylating agent, are disproportionated, alkylated or transalkylated in the presence of a ZSM-22 zeolite. The products of the reactions contain the amounts of the para-isomer which are in excess of the equilibrium amounts of such isomer.
Alternatively, 1,2-disubstituted, 1,3-disubstituted and/or 1,4-disubstituted aromatic compounds are contacted with the ZSM-22 zeolite under cracking conditions to selectively crack the 1,4-disubstituted isomer.

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