Hydrocarbon conversion with low-sodium silicalite

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking

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208118, 208120, 208134, 252455R, 252455Z, 423335, 585648, 585654, C10G 1102, C10G 4702

Patent

active

043092764

ABSTRACT:
Hydrocarbon conversion in the presence of a low-sodium form crystalline silicate converts normal and slightly branched paraffins, at least in part, to olefins.

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patent: 4073865 (1978-02-01), Flanigan et al.
patent: 4171257 (1979-10-01), O'Rear et al.
patent: 4238318 (1980-12-01), Kouwenhoven
"Silicalite, A New Hydrophobic Crystalline Silica Mol Sieve", Flanigan et al., Nature 271, 512-516, (Feb. 9, 1978).
"Silicalite-2, A Silica Analogue of the Aluminosilicate Zeolite ZSM-11", Bibby et al. Nature 280, 664-665, (Aug. 23, 1979).
"Pentasil Family of High-Silica Crystalline Materials", Kokotailo et al., Proceedings of a Conference, pp. 133-139, Apr. 18-20, 1979.
"Chemical and Physical Properties of the ZSM-5 Substitutional Series", Olsen et al., Journal of Catalysis 61, 390-396, (1980).

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