Mineral oils: processes and products – Chemical conversion of hydrocarbons – Reforming
Patent
1979-03-07
1980-07-01
Davis, C.
Mineral oils: processes and products
Chemical conversion of hydrocarbons
Reforming
208111, 208138, 252441, 252466PT, 585419, 585434, 585748, C10G 3508
Patent
active
042105242
ABSTRACT:
Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a catalytically effective amount of a conventional rhenium component and a uniform dispersion of a catalytically effective amount of a platinum group component, which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a conventional rhenium component and a uniform dispersion of a platinum group metal maintained in the elemental state, whereby the interaction of the rhenium carbonyl complex with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with this rhenium reagent. A specific example of the type of hydrocarbon conversion process disclosed herein is a process for the catalytic reforming of a low octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the subject superactive multimetallic catalytic composite at reforming conditions.
REFERENCES:
patent: 3415737 (1968-12-01), Kluksdahl
Davis C.
Hoatson Jr. James R.
McBride Thomas K.
Page II William H.
UOP Inc.
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