Hydrocarbon conversion process and catalysts

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking

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208216PP, 502 67, 502 79, C10G 4712

Patent

active

048571717

ABSTRACT:
A process for converting hydrocarbon oils into products of low average molecular weight and lower average boiling point comprising contacting a hydrocarbon oil at elevated temperature and pressure in the presence of hydrogen with a catalyst comprising a modified Y zeolite having a unit cell size below 24.45 .ANG., a degree of crystallinity which is at least retained at increasing SiO.sub.2 /Al.sub.2 O.sub.3 molar ratios, a water adsorption capacity (at 25.degree. C. and p/p.sub.o value of 0.2) of at least 8% by weight of modified zeolite and a pore volume of at least 0.25 ml/g wherein between 10% and 60% of the total pore volume is made up of pores having a diameter of at least 8 nm, an amorphous cracking component, a binder and at least one hydrogenation component of a Group VI metal and/or at least one hydrogenation component of a Group VIII metal. The invention also relates to catalyst compositions suitable for use in said process.

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"Catalyst Base LZ-Y20 Powder", Union Carbide Molecular Sieves, Zeolite Cat. Data.
"Zeolite Molecular Sieves"; Breck ed; John Wiley & Sons, 1974, p. 177.

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