Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs
Patent
1993-11-02
1995-11-21
Pal, Asok
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
502 64, 502 65, 502 66, 502 68, B01J 2906
Patent
active
054687004
ABSTRACT:
A hydrocarbon conversion catalyst useful for converting hydrocarbon feeds to midbarrel products is prepared by extruding a mixture of an inorganic refractory oxide component and a crystalline aluminosilicate zeolite having cracking activity to form extrudates which are broken into particles normally ranging in length between 1/16 and 1/2 inch. The extruded particles are then calcined in the presence of steam at a water vapor partial pressure greater than about 2.0 p.s.i.a., preferably greater than about 5.0 p.s.i.a. The calcination step is carried out in the presence of sufficient steam for a sufficient amount of time at a sufficient temperature to convert the crystalline aluminosilicate zeolite in the extrudates into an ultrahydrophobic zeolite having a unit cell size between about 24.20 and about 24.45 Angstroms and a sorptive capacity for water vapor less than about 5 weight percent of the zeolite at 25.degree. C. and a p/p.degree. value of 0.10.
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Finkle Yale S.
McBride Thomas K.
Pal Asok
Spears Jr. John F.
UOP
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