Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And additional al or si containing component
Reexamination Certificate
1999-11-09
2004-05-04
Elve, M. Alexandra (Department: 1725)
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
And additional al or si containing component
C502S064000, C502S074000
Reexamination Certificate
active
06730625
ABSTRACT:
FIELD OF INVENTION
This invention relates to a catalyst and process for the hydroalkylation of aromatic hydrocarbons and particularly to a catalyst and process for the hydroalkylation of benzene to produce cyclohexylbenzene.
BACKGROUND TO THE INVENTION
Cyclohexylbenzene can be used to produce phenol, which is one of the most important industrial chemicals in the world. As of December 1995, more than 88% of world phenol capacity was based on cumene peroxidation with acetone coproduction. One of the primary economic difficulties of the cumene peroxidation route is that it requires the existence of an available market for the co-produced acetone. Currently, the growth of market demand for phenol exceeds that for acetone, and hence there exists an acetone oversupply problem. It is expected that this unbalanced growth will continue for some time.
Hydroperoxidation of cyclohexylbenzene (analogous to cumene peroxidation) could offer an alternative route for phenol production without the problem of acetone co-production. This alternative route co-produces cyclohexanone, which is a much more valuable and desirable by-product than acetone. Thus, cyclohexanone is used partly for the manufacture of caprolactam and nylon, the same market that much phenol is intended for.
Dehydrogenation of cyclohexylbenzene also offers a low cost alternative to produce diphenyl from benzene. Diphenyl is used mainly for heat-transfer applications. Currently the main source of diphenyl is as a by-product (1 g diphenyl/100 g benzene) in benzene production by toluene dealkylation. The crude diphenyl is refined to 93-97% purity by distillation. High purity diphenyl can also be produced by direct thermal dehydrocondensation of benzene at 700-800° C. in gas or electrically heated tubular reactors. This process is energy intensive and produces by-products of terphenyl, higher polyphenyls and tars.
It is known that cyclohexylbenzene can be produced from benzene by the process of hydroalkylation or reductive alkylation In this process, benzene is heated with hydrogen in the presence of a catalyst such that the benzene undergoes partial hydrogenation to produce cyclohexene which then alkylates the benzene starting material. Thus U.S. Pat. Nos. 4,094,918 and 4,177,165 disclose hydroalkylation of aromatic hydrocarbons over catalysts which comprise nickel- and rare earth-treated zeolites and a palladium promoter. Similarly, U.S. Pat. Nos. 4,122,125 and 4,206,082 disclose the use of ruthenium and nickel compounds supported on rare earth-treated zeolites as aromatic hydroalkylation catalysts. The zeolites employed in these prior art processes are zeolites X and Y. More recently, U.S. Pat. No. 5,053,571 has proposed the use of ruthenium and nickel supported on zeolite beta as an aromatic hydroalkylation catalyst. However, existing proposals for the hydroalkylation of benzene suffer from the problems that the selectivity to cyclohexylbenzene is low particularly at economically viable benzene conversion rates and that large quantities of unwanted by-products, particularly cyclohexane and methylcyclopentane, are produced.
An object of the present invention is to provide a process for the hydroalkylation of aromatic hydrocarbons with an improved selectivity for the desired cycloalkyl-substituted aromatic hydrocarbon, particularly cyclohexylbenzene, and decreased production of by-products such as cyclohexane and methylcyclopentane.
SUMMARY OF THE INVENTION
According to one aspect of the invention there is provided a process for the hydroalkylation of an aromatic hydrocarbon comprising the step of contacting the aromatic hydrocarbon with hydrogen in the presence of a dual-functional catalyst comprising a first metal having hydrogenation activity and a crystalline inorganic oxide material having a X-ray diffraction pattern including the d-spacing maxima at 12.4±025, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom.
Preferably, the aromatic hydrocarbon is benzene.
Preferably, the crystalline inorganic oxide material is MCM-22.
Preferably, the first metal is selected from palladium, ruthenium, nickel and cobalt.
Preferably, the catalyst also contains a second metal, different from the first metal, and selected from zinc, tin, nickel and cobalt.
In a further aspect, the invention resides in a catalyst suitable for the hydroalkylation of an aromatic hydrocarbon comprising
(a) a first metal having hydrogenation activity and selected from palladium, ruthenium, nickel and cobalt;
(b) a second metal, different from the first metal, and selected from zinc, tin, nickel and cobalt; and
(c) a crystalline inorganic oxide material having a X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom.
DETAILED DESCRIPTION OF THE INVENTION
This invention relates to a catalyst and process for the hydroalkylation of aromatic hydrocarbons, particularly benzene, to cycloalkylphenyl compounds, particularly cyclohexylbenzene, using as the catalyst a hydrogenation metal-containing crystalline inorganic oxide material having a X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom. The X-ray diffraction data used throughout this specification were obtained by standard techniques using the K-alpha doublet of copper as the incident radiation and a diffractometer equipped with a scintillation counter and associated computer as the collection system.
Suitable inorganic oxide materials are MCM-22 (described in U.S. Pat. No. 4,954,325), PSH-3 (described in U.S. Pat. No. 4,439.409), SSZ-25 (described in U.S. Pat. No. 4,826,667), MCM-36 (described in U.S. Pat. No. 5,250,277), MCM-49 (described in U.S. Pat. No. 5,236,575) and MCM-56 (described in U.S. Pat. No. 5,362,697), with MCM-22 being particularly preferred.
The hydrogenation metal is preferably selected from palladium, ruthenium, nickel, cobalt and mixtures thereof, with palladium and ruthenium being particularly preferred. In addition, the catalyst may contain a further hydrogenation metal, such as platinum, rhodium and rhenium, in addition to said preferred hydrogenation metals. The amount of hydrogenation metal present in the catalyst may vary significantly and will, for example, depend on the particular metal employed. Preferably, however, the amount of hydrogenation metal present is between 0.05 and 10 wt %, and more preferably between 0.1 and 5 wt %, of the catalyst.
The catalyst preferably contains a second metal component, in addition to and different from the hydrogenation metal, which acts to promote the hydrogenation function of the catalyst. Suitable second metal components are selected from zinc, tin, nickel, cobalt and mixtures thereof. Again, the amount of second metal component present in the catalyst may vary significantly but preferably is between 0.05 and 10 wt %, and more preferably between 0.1 and 5 wt %, of the catalyst.
The catalyst of the invention may also include a matrix or binder which is composited with the inorganic oxide material. Such matrix materials include synthetic or naturally occurring substances as well as inorganic materials such as clay, silica and/or metal oxides. The latter may be either naturally occurring or in the form of gelatinous precipitates or gels including mixtures of silica and metal oxides. Naturally occurring clays which can be composited with the inorganic oxide material include those of the montmorillonite and kaolin families, which families include the subbentonites and the kaolins commonly known as Dixie, McNamee, Georgia and Florida clays or others in which the main mineral constituent is halloysite, kaolinite, dickite, nacrite or anauxite. Such clays can be used in the raw state as originally mined or initially subjected to calcination, acid treatment or chemical modification.
In addition to the foregoing materials, the inorganic oxide material employed herein may be composited with a porous matrix material, such as silica, alumina, zirconia, titania, silica-alumina
Chang Clarence D.
Cheng Jane C.
Helton Terry E.
Steckel Michael A.
Stevenson Scott A.
Elve M. Alexandra
ExxonMobil Oil Corporation
Ildebrando Christina
Kubena Linda A.
Tyus Darryl M.
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