Hydroalkylation of aromatic hydrocarbons

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Hydrocarbon is aromatic

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585268, 585269, 585446, C07C 266

Patent

active

051460246

ABSTRACT:
A process for converting aromatic hydrocarbons (in particular benzene) to cycloalkyl-substituted aromatic hydrocarbons (in particular cyclohexylbenzene) in the presence of free hydrogen and a palladium-promoted zeolite catalyst is carried out in the presence of carbon monoxide as process modifier (so as to enhance the selectivity to the cycloalkyl-substituted aromatic hydrocarbon).

REFERENCES:
patent: 3412165 (1968-11-01), Slaugh et al.
patent: 3760017 (1973-09-01), Arkell et al.
patent: 3760019 (1973-09-01), Crome, Jr. et al.
patent: 4094918 (1978-06-01), Murtha et al.

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