Hydridomethyl iridium complex

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 22, 570235, C07F 1500

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active

048495344

ABSTRACT:
A process for functionalizing methane comprising:

REFERENCES:
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Janowicz, A. H. et al., "C-H Activation in Completely Saturated Hydrocarbons: Direct Observation of M+R-H.fwdarw.M(R)(H)", J. Am. Chem. Soc. 1982, 104, 352-354.
Bergman, R. G. "Activation of Alkanes with Organotransition Metal Complexes", Science, Mar. 2, 1984, vol. 223, pp. 902-908.
Janowicz, A. H. et al., "Oxidative Addition of Soluble Iridium and Rhodium Complexes to Carbon-Hydrogen Bonds in Methane and Higher Alkanes", Pure & Appl. Chem., vol. 56, No. 1, pp. 13-23, 1984.
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Periana, R. A. et al., "Rapid Intramolecular Rearrangement . . . Cationic Rhodium .pi.-Allyl Complex", J. Am. Chem. Soc. 1984, 106, pp. 7272-7273.
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Hoyano, J. K. et al., "Oxidative Addition of the Carbon-Hydrogen Bonds . . . Photochemically Generated Iridium(I) Complex", J. Am. Chem. Soc. 1982, 104, pp. 3723-3725.
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