Hydridometallic carborane catalytic compounds

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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260429R, 2604482B, 260497R, 260526R, 260561R, 260604HF, B01J 3112, C07F 1500

Patent

active

039765962

ABSTRACT:
A family of stable hydrido-rhodium and iridium carboranes are described which are effective catalysts for the homogeneous hydrogenation, isomerization and hydroformylation of olefins and the hydrosilylation of ketones.

REFERENCES:
patent: 3418346 (1968-12-01), Parshall
patent: 3458547 (1969-07-01), Coffey
patent: 3515757 (1970-06-01), Sibert
patent: 3547984 (1970-12-01), Young
Grimes, Carboranes, Academic Press, N.Y. pp. 207-249 (1970).
Kosolapoff et al., Organic Phosphorus Compounds, Wiley-Interscience, N.Y. vol. 1, pp. 488-489 (1972).
Booth, Advances in Inorganic Chem. and Radiochem. vol. 6, pp. 23 to 26, 1964.
J.A.C.S. V 88, pp. 2272-2282 (1966).
J.A.C.S. V 94, pp. 6679-6682 (1972).
Science, V 178, p. 462 (1972).

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