Hydrides of lithiated nickel dioxide and secondary cells prepare

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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423593, 429223, 429221, 429224, C01B 624

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active

051805740

ABSTRACT:
Hydrides of lithiated nickel dioxide are disclosed, prepared by providing a substantially homogeneous dry intermediate mixture of a starting material containing a nickel compound selected from nickel oxide, nickel hydroxide and mixtures thereof, and optionally including one or more oxides or hydroxides of a transition metal selected from cobalt, iron, chromium, titanium, manganese and vanadium, together with about a 25% stoichiometric excess of lithium hydroxide. The mixture is heat-treated at a temperature above about 600.degree. C. in an atmosphere having a partial pressure of water vapor greater than about two torr. Electrochemical cells are also disclosed, incorporating the disclosed hydrides as a cathode-active material.

REFERENCES:
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Dyer et al., JACS, 76, 1499-1503 (1954).
Bronger et al., Z. Anorg. Allg. Chem., 333, 188-200 (1956).
Goodenough et al., J. Phys. Chem. Solids, 5, 107-16 (1958).
Goodenough et al., J. App. Phys., 29(3), 382-3 (1958).
Fensham, JACS, 76, 969-71 (1954).

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