Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1974-01-04
1976-01-13
Davis, C.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260559S, 423 24, 423 99, 423139, C07C10326
Patent
active
039325059
ABSTRACT:
A compound having the general formula ##SPC1##
In which R.sup.1 , R.sup.2, R.sup.3 and R.sup.4 may be the same or different and represent hydrogen, a straight or branched chain alkyl radical having 1 to 20 carbon atoms, an aralkyl radical having 7 to 20 carbon atoms which may be substituted by one or more alkyl groups having 1 to 4 carbon atoms, or may be of the type: ##SPC2##
Wherein R.sup.5 and R.sup.6 are each a hydrogen atom or a methyl group, and each R represents the others of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, an alkenyl radical having 2 to 20 carbon atoms; a cycloalkyl radical having 5 to 12 carbon atoms which may be substituted by one or more alkyl groups having 1 to 4 carbon atoms; an aryl radical having 6 to 10 carbon atoms; an alkaryl radical having 7 to 12 carbon atoms; a cyclohexyl alkyl radical in which the alkyl moiety has 2 or 3 carbon atoms and the cyclohexenyl ring may contain a methyl group as substituent; an alkenyl cyclohexyl radical in which the alkenyl moiety has 2 or 3 carbon atoms and the cyclohexyl ring may also contain a methyl group as substituent; or a group -OR.sup.7 wherein R.sup.7 represents an alkyl radical having 1 to 20 carbon atoms, a cycloalkyl radical having 5 to 12 carbon atoms, optionally substituted by one or more alkyl groups having 1 to 4 carbon atoms, an aryl radical having 6 to 10 carbon atoms or an alkenyl radical having 3 to 20 carbon atoms; or any two adjacent radicals R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may be joined together to form an aryl ring which may be substituted by one or more alkyl groups having 1 to 20 carbon atoms; X represents an anion; and n is the valency of X, is useful for the extraction of metals from aqueous solutions.
REFERENCES:
patent: 2716663 (1955-08-01), Beman
patent: 2763684 (1956-09-01), Beman
Beilsteins Handbuch Der Organischen Chemie, Vol. X, p. 161 (1971).
Issa et al., 2. Anorg. Allq. Chem., 354, 90 (1967).
Shome et al., Anal. Chim Acta, 32(4), 400 (1965).
Baylis Eric Keith
Pickles Wilfred
Ciba-Geigy Corporation
Davis C.
Hall Luther A. R.
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