Plant protecting and regulating compositions – Plant growth regulating compositions – Organic active compound containing
Reexamination Certificate
2000-07-25
2001-12-11
Clardy, S. Mark (Department: 1616)
Plant protecting and regulating compositions
Plant growth regulating compositions
Organic active compound containing
C504S365000, C514S937000
Reexamination Certificate
active
06329322
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to the use of phosphate and phosphonate amphoteric surfactants having multiple ionic charges to increase the stability of bioactive compositions and enhance the bioefficacy of the active.
BACKGROUND OF THE INVENTION
Numerous organic bioactives, especially pesticides, i.e., chemicals that are useful in the control of insects, fungi, weeds, and the like have been developed in recent years. Regardless of whether the pesticide is inherently water soluble or water insoluble, it is desirable to use the same in an aqueous medium rather than in a non-aqueous solvent which is more difficult to use by the formulator and applicator, could cause environmental damage, is more costly and is in general, less desirable. Water-based dispersions, emulsions, and/or solutions can be prepared from most pesticides using selected surfactants. Proper selection of the surfactant can also improve the efficacy of pesticidal compositions.
Surfactants have proven to be especially useful in the preparation of herbicidal compositions whether the herbicide is water soluble or insoluble. When the herbicide is water insoluble, the surfactant can be used to make a water dispersible herbicide composition. When the herbicide is water soluble, the surfactant can often be used to improve the herbicidal effectiveness of the herbicidal composition.
One class of surfactants that has found much commercial success in the preparation of herbicidal compositions includes the polyoxyalkylene alkylamines. These compounds have the necessary surface activity so that many otherwise water insoluble herbicides, as well as water soluble herbicides, can be formulated into concentrates which will form useful dispersions, emulsions, and solutions in water. In addition, herbicides formulated into dispersions, emulsions, and solutions using these surfactants often have improved herbicidal properties.
However, while the polyoxyalkylene alkylamine compounds have excellent surfactant properties and often enhance the bioefficacy of phytotoxicants, they unfortunately are irritants, especially producing eye irritation and must be used with a high degree of caution.
Many efforts have been made to reduce the irritancy of the polyoxy alkylene alkylamine compounds while still retaining their surfactant effectiveness in stabilizing agricultural formulations and enhancing bioeffectiveness. Most of these efforts entail the addition of multiple surfactant compounds to the alkylamine—bioactive composition.
Perhaps the most widely used herbicide worldwide is glyphosate, which chemically is N-phosphonomethylglycine. This product is normally used in an agriculturally acceptable form, such as a water soluble salt, e.g., the isopropylamine salt. Often used surfactants for the preparation of glyphosate concentrates, which can then be diluted with water for use by the applicator, are the aforementioned polyoxyalkylene alkylamines, especially the ethoxylated tallow amines.
It is therefore an object of the present invention to provide stable surfactant containing bioactive compositions with enhanced bioeffectiveness.
Another object of the present invention is to provide stable pesticidal compositions, especially herbicidal compositions, and most especially those containing glyphosate, having agriculturally acceptable efficacy and reduced eye irritation.
Another object of the present invention is to provide new methods for controlling the growth of weeds and other vegetation.
Other objects of the present invention will become apparent from the following description.
SUMMARY OF THE INVENTION
The present invention is directed to bioactive compositions, particularly pesticidal compositions, and most particularly herbicidal compositions comprising a pesticide, such as a herbicide, and a surfactant composition comprising a phosphate or phosphonate amphoteric surfactant having multiple ionic charges. These compositions are readily dispersible in water so as to prepare extremely stable, aqueous compositions useful for, among other things, the control of weeds, insects, fungi, and the like in the absence of severe eye irritancy such as is associated with the use of the polyoxyalkylated alkylamine surfactants.
In accordance with a preferred embodiment of the present invention, an aqueous solution is provided which comprises a herbicidally effective amount of a glyphosate herbicide, either in acid or salt form, whose composition is stabilized and whose herbicidal effectiveness is enhanced by the presence of a potentiality effective amount of the phosphate or phosphonate amphoteric surfactant of the instant invention.
DETAILED DESCRIPTION OF THE INVENTION
The compositions of the instant invention comprise a bioactive, especially an ionic bioactive, and most especially a pesticidal polyionic bioactive and an effective amount of a phosphate or phosphonate amphoteric surfactant having multiple ionic charges. It has been discovered that these amphoteric surfactants increase the stability and enhance the bioeffectiveness of bioactives in aqueous compositions.
Amphoterics are, by definition, surfactants which, depending on the pH, can have anionic and/or cationic properties in aqueous medium. An amphoteric contains at least one acidic group and at least one basic group. The pH where these groups internally neutralize each other, producing a zwitterion (a cationic and anionic group in the same molecule), is called the isoelectric point (or isoelectric area). At pH above the isoelectric area, amphoterics act as anions and below the isoelectric area they act as cations with external counter ions (cations and anions, respectively).
The cationic functionality is generally a protonated secondary or tertiary amine group (in so-called weak nitrogen amphoterics), or a quaternary ammonium group (in strong nitrogen amphoterics or alkylbetaines). Weak nitrogen amphoterics are protonated only at lower pH levels whilst alkyl betaines retain their positive charge over virtually the whole pH range. At least one anionic group in the surfactant molecules of this invention is a phosphate or phosphonate moiety. Commonly and additionally other anionic groups such as a carboxylate, sometimes sulfonate or sulfate groups, and additional phosphate and/or phosphonate moieties are also present.
Amphoteric surfactants may have an equal or unequal number of anionic and cationic groups with the charge balanced by external counter ions. The number of such groups influences the isoelectric area, as does the ionic strength of such groups.
The primary source for the cationic functionality in the phosphate or phosphonate amphoterics of the instant invention is a nitrogen containing moiety. Preferably the moiety is an amine, an aminoalkyl, amido, aminoalkyl, amine oxide, or quaternary ammonium group.
Preferred phosphate or phosphonate amphoteric surfactant compositions useful in the instant invention are those of the formula:
R
1
and R
2
independently, are selected from the group consisting of substituted or unsubstituted C
1
to C
36
straight or branched chain alkyl, alkenyl, aryl, alkylaryl, arylalkyl and mixtures thereof, wherein said R
1
and R
2
are optionally further characterized as containing ether, thioether, polyoxyalkylene oxide, amine, amine oxide, quaternary ammonium, amide, alkylamine, alkylamide, carbonyl or ester groups, or are substituted thereby with open valences filled by R
3
wherein R
3
is hydrogen or R
1
;
R independently is H, C
1-18
alkyl, alkenyl, aryl, alkaryl, or arylalkyl; optionally containing ether groups;
R
4
is independently H, C
1-18
alkyl, alkenyl, aryl, alkaryl, or arylalkyl;
R
5
is independently OH, OY, A, or OR
4
wherein A is
Y is H, or a counterion which, when needed to balance a charge, is an alkali metal, alkali earth metal, protonated amine, or quaternary ammonium counterion,
Z is independently H, C
1-18
alkyl, alkenyl, aryl, alkylaryl, arylalkyl, or oxygen;
n is independently a whole number from 2 to about 4;
t and t′ are independently 0 or 1;
m is 0 to 10;
v is 1 and v′ is independently 0 or 1;
w a
Clardy S. Mark
Rhodia Inc.
Shedden John A.
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