Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
1998-10-02
2001-10-02
Nutter, Nathan M. (Department: 1711)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
C524S481000, C524S483000, C524S487000, C524S489000, C524S490000, C604S358000, C604S366000
Reexamination Certificate
active
06297309
ABSTRACT:
This application is the National Phase of International Patent Application PCT/FR96/01424, filed Sep. 13, 1996, which claims priority to French Patent Application 95.11252, filed Sep. 26, 1995, the entire contents of each are hereby incorporated by reference in their entirety and relied upon.
FIELD OF THE INVENTION
The present invention relates to a pressure-sensitive hot-melt adhesive composition, to its use in the field of hygiene and to the adhesively bonded articles thus obtained, especially disposable nappies or diapers and catamenial liners.
BACKGROUND OF THE INVENTION
Disposable nappies generally consist of an absorbent filler protected on its outer face by a liquidproof polyethylene film and covered internally with a film of nonwoven fabric, generally of polyethylene, which comes into contact with the skin and allows body fluids to flow towards the said filler. More elaborate nappies may, in addition, contain a leakproof barrier of polyolefinic nature and/or an elastic waistband.
The nappies are conventionally prepared by adhesively bonding the various constituents with the aid of hot-melt adhesives whose composition can vary depending on the chemical nature of the components to be assembled. Such adhesives are described, for example, in the documents which follow.
U.S. Pat. No. 4,526,577 proposes an adhesive including a block copolymer A-B-A (in which A denotes a nonelastomeric block, for example styrene, and B denotes butadiene or hydrogenated butadiene), a compatible tackifying resin, a plasticizing oil and a stabilizer and, optionally, a wax originating from petroleum.
U.S. Pat. No. 4,460,728 describes an adhesive based on an ethylene-vinyl acetate or alkyl acrylate copolymer, on atactic polypropylene and on a compatible tackifying resin, optionally in the presence of a plasticizing oil and/or of a wax originating from petroleum and/or of a stabilizer.
U.S. Pat. No. 4,939,202 proposes a moisture-resistant adhesive containing a propylene-based amorphous polymer, a propylene-based crystalline polymer and a petroleum resin containing hydrocarbons containing from 4 to 10 carbon atoms.
U.S. Pat. No. 4,149,741 employs a hot-metal adhesive including a styrene-isoprene-styrene block copolymer, a compatible tackifying resin, a plasticizing oil and a stabilizer and, optionally, a wax derived from petroleum.
Catamenial liners, for their part, generally include an absorbent filler of the cellulose fluff or superabsorbent type and a covering based on a nonwoven fabric made of polypropylene or of viscose, to the outer face of which covering an adhesive composition is applied allowing positioning on the undergarment. To manufacture such liners the compositions described in the following documents have been proposed.
EP 0104005-A proposes an adhesive based on a viscoelastic elastomer of A-B-A type (in which B denotes a polyolefin, for example an ethylene-butylene copolymer and A includes a polystyrene), and on a tackifying resin.
Finally, in WO 93/10734 a composition is described including a copolymer of formula (A-B)
n
-Y (in which Y is a multivalent coupling agent, A is a vinyl monomer substituted by an aromatic radical and B is polybutadiene), a compatible tackifying resin and a plasticizing oil.
The adhesives of the prior art which have just been mentioned are not entirely satisfactory in the field of hygiene.
Thus, in the case of disposable nappies, the polypropylene-based hot-melt adhesives (U.S. Pat. No. 4,460,728 and U.S. Pat. No. 4,939,202) are difficult to use in conventional devices operating by fiberizing or spraying, and the compositions described in U.S. Pat. No. 4,526,577 and U.S. Pat. No. 5,149,741 exhibit poor behaviour towards water, which can result in particular in the separation of the absorbent filler adjoining the leakproof film.
In the case of catamenial liners the abovementioned adhesive compositions are found to be satisfactory when applied to a covering made of nonwoven fabric. However, it is found that the said compositions are not suited for the preparation of latest-generation ultrafine liners which comprise a covering consisting of a polyethylene-based open-worked or perforated film. It is found, in fact, that the use of compositions based on ethylene-vinyl acetate copolymer results in soiling of the covering and that the adhesives according to EP 0 104 005-A and WO 93/10734 must be applied at an elevated temperature, of the order of 150 to 180° C., in order to adhere to the support in a satisfactory manner.
DESCRIPTION OF THE INVENTION
New pressure-sensitive thermoplastic adhesive compositions have now been found which do not exhibit the abovementioned disadvantages, these compositions being characterized in that they include
a) at least one ethylene-alkyl acrylate copolymer
b) a tackifying resin
c) optionally a diluent and/or a stabilizer and/or a wax.
The ethylene-alkyl acrylate copolymer according to the invention is generally chosen from copolymers containing from 15 to 45% and preferably 25 to 35% by weight of alkyl acrylate.
The alkyl acrylate is advantageously chosen from methyl acrylate, butyl acrylate and 2-ethylhexyl acrylate. Butyl acrylate is preferably employed.
Such copolymers which exhibit a melt index of between 0.5 and 1000 and preferably 2 and 500 are generally employed.
Among the abovementioned copolymer mixtures which can be employed it is possible to mention very particularly the mixtures based on copolymer exhibiting an acrylate content of between 15 and 40%, preferably 30 and 35, and a melt index of between 500 and 2, preferably 320 and 2.
The tackifying resin according to the invention is chosen from the group consisting of solid or liquid hydrocarbon resins such as the unhydrogenated or completely or partially hydrogenated aliphatic or aromatic resins, for example ESCOREZ 5300 form Exxon and IMARV S 100 S form Idemitzu, resins based on natural or modified, for example polymerized, rosin esters, especially pentaerythritol or glycerol esters, for example UNITAC R 100 L form Union-Camp, polyterpene or modified polyterpene resins, for example WINGTACK from Goodyear and “-methylstyrene resins, for example URATACK 68520 from DSM.
The diluent according to the invention is chosen from aliphatic or naphthenic oils, plasticizers such as phthalates, adipates and benzoates, oligomeric or polymeric olefins of low molecular weight, polypropylene, polybutene and hydrogenated polyisoprene.
The wax according to the invention is generally chosen from waxes of petroleum origin or from Fischer Tropsch synthesis.
The stabilizer according to the invention is generally chosen from antioxidants such as substituted phenols, for example IRGANOX 1076 from Ciba-Geigy and phosphites.
The pressure-sensitive hot-melt adhesive composition in accordance with the invention generally includes from 20 to 50% by weight, and preferably 30 to 40%, of ethylene-alkyl acrylate copolymer, from 30 to 80% by weight, and preferably 40 to 60%, of tackifying resin, from 0 to 35% by weight, and preferably 10 to 25%, of diluent, from 0 to 1.5% by weight of stabilizer and from 0 to 15% by weight of wax.
Compositions according to the invention advantageously exhibit a viscosity of between 1000 and 10,000 mPa s (Brookfield viscometer—temperature 150-170° C.).
The compositions in accordance with the invention are generally obtained by mixing at a temperature which varies from 120 to 170° C.
The compositions thus obtained exhibit good adhesive to polyolefinic supports such as films and nonwoven fabrics made of polyethylene or polypropylene, good cohesion and good water resistance. In addition, these compositions can be processed very easily according to the techniques in the field of hygiene, in particular by coating, fiberizing, spraying or control-coating.
The pressure-sensitive hot-melt adhesive compositions according to the invention are particularly recommended for the manufacture of articles related to the field of hygiene, especially of disposable nappies and of catamenial liners, which articles also constitute a subject-matter of the invention. These compositions are ad
Bauduin Francois
Dreyfus Thierry
Godec Catherine
Elf Atochem S.A.
Nutter Nathan M.
Smith , Gambrell & Russell, LLP
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