Catalyst – solid sorbent – or support therefor: product or process – Miscellaneous
Reexamination Certificate
2001-11-19
2004-08-03
Silverman, Stanley S. (Department: 1754)
Catalyst, solid sorbent, or support therefor: product or process
Miscellaneous
C502S527190
Reexamination Certificate
active
06770591
ABSTRACT:
BACKGROUND OF THE INVENTION
Field of the Invention
The present invention relates to a honeycomb body which is produced from layered or wound sheet-metal layers, as is used in particular as a catalyst carrier body for exhaust gas-cleaning systems. Such honeycomb bodies are typically produced from alternating layers of smooth and corrugated sheets or from alternating layers of differently structured metal sheets, by winding or layering. Honeycomb bodies of that type are described, for example, in International Publication No. WO 94/13939, corresponding to U.S. Pat. Nos. 5,729,902 and 5,618,501.
Since high temperatures and a corrosive environment typically prevail in exhaust gas systems of internal-combustion engines, heretofore alloys which are resistant to high-temperature corrosion, i.e. steel alloys with a high chromium and aluminum content, have substantially been used as materials for honeycomb bodies of that type.
Although it is generally known that stainless steels with an increasing aluminum content become more and more difficult to process, as a result of which the material has to be constantly re-annealed during a rolling process, a trend toward higher aluminum contents in metallic honeycomb bodies has nevertheless started to emerge. That can be learned, for example, from U.S. Pat. No. 4,602,001, in which it is attempted to compensate for the difficulty of processing steel with a high aluminum content by only adding the aluminum subsequently through the use of additional aluminum layers and diffusion.
German Published, Non-Prosecuted Patent Application DE 44 10 744 A1 has also revealed a trend toward high aluminum contents, although the electrical properties are to the fore in that case.
At the same time, there is a discernible trend toward thinner sheet-metal layers, since a lower mass in a catalyst carrier body has a beneficial effect on the cold-starting performance, and thin walls cause a lower pressure loss. However, the thinner the sheet-metal layers become, the less favorable the ratio of aluminum to surface area, which is the decisive criterion for the long-term corrosion resistance of the sheet-metal layers. That explains the trend toward increasing aluminum contents with relatively thin foils, even though it makes the rolling processes considerably more difficult.
The trend toward increasingly thin metal sheets in honeycomb bodies can also be learned, for example, from German Published, Non-Prosecuted Patent Application DE 44 18 630 A1.
In the meantime, however, it has emerged that there are special applications for metallic honeycomb bodies in which the above considerations do not apply. Those are, in particular, applications for the exhaust systems of motorcycles, in which the mechanical loads are so great that thicker foils have to be used. Moreover, there are applications for metallic honeycomb bodies in exhaust gas-cleaning systems of diesel engines, in which the temperatures that prevail are much lower than in the exhaust systems of spark-ignition engines. Therefore, the general considerations relating to other applications of honeycomb bodies do not necessarily apply for both applications.
SUMMARY OF THE INVENTION
It is accordingly an object of the invention to provide a honeycomb body, in particular a catalyst carrier body, for motorcycle or diesel applications, which overcomes the hereinafore-mentioned disadvantages of the heretofore-known devices of this general type and which can be produced at particularly low cost, for precisely these applications.
With the foregoing and other objects in view there is provided, in accordance with the invention, a honeycomb body, in particular a catalyst carrier body for exhaust gas-cleaning systems of motorcycles, comprising layered or wound sheet-metal layers at least partially structured to form passages through which exhaust gas can flow. The sheet-metal layers are formed of a stainless steel, have a thickness of more than 0.08 mm and have an aluminum content in percent by weight of between 6 and 12% multiplied by 0.02 mm divided by the thickness of the sheet-metal layers.
With the objects of the invention in view, there is also provided a honeycomb body, in particular a catalyst carrier body for exhaust gas-cleaning systems of motorcycles, comprising layered or wound sheet-metal layers at least partially structured to form passages through which exhaust gas can flow. The sheet-metal layers are formed of a stainless steel containing 15-25% (percent by weight) of chromium, 0.02 to 0.2% of rare earths, in particular yttrium and/or lanthanum and/or cerium, have between 1 and 4.5% of aluminum and have a thickness of more than 0.08 mm.
With the objects of the invention in view, there is additionally provided a honeycomb body acting as a catalyst carrier body for exhaust gas-cleaning systems of diesel vehicles, comprising layered or wound sheet-metal layers at least partially structured to form passages through which exhaust gas can flow. The sheet-metal layers are formed of a stainless steel containing 15-25% (percent by weight) of chromium, 0.02 to 0.2% of rare earths, in particular yttrium and/or lanthanum and/or cerium, and have between 1 and 4.5% of aluminum.
Recent developments in the production of metal sheets with high aluminum contents are based on multistage processes, in which first of all steel sheet with a relatively low aluminum content is rolled down to a defined thickness and then, in a second part of the process, the aluminum content is increased and the final thickness is achieved. The aluminum content can be increased by rolling-on aluminum foil or by hot-dip aluminizing or by aluminum dipping processes. Over the course of production processes of this type, rolling processes have been developed which enable steels with an aluminum content of at most 4.5% to be rolled at relatively low cost, in particular without frequent intermediate annealing.
The present invention makes use of the discovery that materials of this type, despite having an aluminum content of below 4.5 or even below 4%, are sufficiently resistant to high-temperature corrosion if they are used in honeycomb bodies with a thickness of the sheet-metal layers of more than 0.06 mm, preferably more than 0.08 mm. With sheet-metal layers of a thickness of this nature, the ratio of the total aluminum present to the surface area, for an aluminum content of 3 or 4%, is in fact better than for sheet-metal layers with a thickness of, for example, 0.03 mm and an aluminum content of 6%. Since aluminum diffuses very rapidly in steel at high temperatures, sufficient aluminum reaches the surface, even with relatively low aluminum contents in thick sheet-metal layers, to compensate for any damage to a protective oxide layer by forming further aluminum oxide.
There is an approximation formula for sheet-metal layers with a thickness of over 0.06 mm, according to which the aluminum content (in percent by weight) should be between 6 and 12%, in particular between 8 and 10%, multiplied by 0.02 mm divided by the thickness of the sheet-metal layers. In this way, the ratio of total aluminum present to the surface area in these metal sheets is always better than in a metal sheet with a thickness of 0.02 mm and an aluminum content of 6%.
The high mechanical loads in exhaust gas-cleaning systems of motorcycles and some applications require the use of metal sheets with a thickness of between 0.08 and 0.12 mm. Therefore, metal sheets with an aluminum content of from 1 to 4.5% are suitable for these applications. Steel sheets of this type typically have a chromium content of from 15 to 25% and a certain level of rare earths. The known conditions for these and other fractions in stainless steels also apply in the present case.
Naturally, relatively thick sheet-metal layers cannot be used to produce extremely fine structures, and consequently the honeycomb bodies according to the invention typically have between 200 and 600 cpsi (cells per square inch).
A particular economic benefit of the present invention is that the material for catalyst carrier bodies for motorc
Emitec Gesellschaft fuer Emissions-technologie mbH
Silverman Stanley S.
Strickland Jonas N.
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