Homogenous catalyst and process for liquid phase isomerization a

Details Homogenous catalyst and process for liquid phase isomerization a Homogenous catalyst and process for liquid phase isomerization a

1992-12-21

1995-04-11

McFarlane, Anthony

Chemistry of hydrocarbon compounds

Saturated compound synthesis

By condensation of a paraffin molecule with an olefin-acting...

528727, 528728, 528734, 528741, 528747, C07C 260, C07C 527

Patent

active

054060184

ABSTRACT:
A discrete catalyst and processes for the isomerization of alkanes and the alkylation of isoalkanes under homogenous fluid conditions. The catalyst is formed by contacting, under fluid conditions, a homogenous fluid containing a paraffin hydrocarbon having from 4 to 12 carbon atoms with a Lewis acid/protic Bronsted acid pair and a transition metal to produce a discrete catalytic complex that is soluble in the fluid. The discrete catalyst is the reaction product of the acid pair and alkanes and includes hydrocarbon ligands of limited chain length rendering it soluble in the fluid. The catalyst is active for the isomerization of alkanes and olefins, and the alkylation of isoalkanes, under homogenus fluid conditions.

REFERENCES:
patent: 3470264 (1969-09-01), Mayhue
patent: 3862257 (1975-01-01), Buben et al.
patent: 3873635 (1975-03-01), Prescott et al.
patent: 3880945 (1975-04-01), Kramer et al.
patent: 4120912 (1978-10-01), Hulme

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