Homogeneous, low-temperature transition metal-mediated synthesis

Details Homogeneous, low-temperature transition metal-mediated synthesis Homogeneous, low-temperature transition metal-mediated synthesis

1994-02-10

1994-10-25

Brust, Joseph Paul

Organic compounds -- part of the class 532-570 series

Organic compounds

Nitriles

558317, C07C25300

Patent

active

053591194

ABSTRACT:
A low temperature, solution phase process for synthesizing nitriles such as acrylonitrile and benzylnitrile is provided which makes use of a transition metal complex bearing an imido moiety to form a final nitrile corresponding to the moiety. In practice, a solution of a transition metal complex is formed in a non-interfering solvent, and the solution is reacted under time and temperature conditions to form the desired nitrile. The solution may also contain a base such as pyridine.

REFERENCES:
Maatta, et al., J. A. C. S., 110, (1988), pp. 8249-8250.
Maatta et al., J. Chem. Soc., Chem. Communications, Issue 10, (1990), pp. 756-757.
Burrington, et al., Journal of Catalysis, 87, (1984), pp. 363-380.

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