Hollow acrylate polymer microspheres

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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428402, 523223, 524801, 521 56, 521 63, 521 64, 521149, C08J 932, B01J 1302

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active

050455699

ABSTRACT:
Hollow, polymeric, acrylate, infusible, inherently tacky, solvent-insoluble, solvent-dispersible, elastomeric pressure-sensitive adhesive microspheres having an average diameter of at least about 1 micrometer. Preferred microspheres are those wherein a majority of the hollow microspheres contain at least one of interior void having a diamter of at least 10% of the diameter of the microsphere.
These hollow microspheres are useful as repositionable pressure-sensitive adhesives. The invention also provides pressure-sensitive adhesives consisting essentially of such hollow microspheres. Aqueous suspensions of these microspheres, processes for their preparation, spray repositionable pressure-sensitive adhesive compositions, and microsphere-coated sheet materials are also provided. Surprisingly, hollow microspheres of the invention show reduced or even eliminated adhesive transfer, in comparison with prior art repositionable pressure-sensitive adhesives which are based on solid microspheres.

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Surfactant Systems: Their chemistry, pharmacy and biology, D. Attwood and A. T. Florence, Chapman and Hall, N.Y., N.Y., 1983.

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