Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By skeletal isomerization
Patent
1992-08-11
1993-08-17
Garvin, Patrick P.
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
By skeletal isomerization
C07C 522, C07C 527
Patent
active
052371212
ABSTRACT:
A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.
REFERENCES:
patent: 4912073 (1990-03-01), Chu
patent: 4922048 (1990-05-01), Harandi
patent: 5157194 (1992-10-01), Rahnin et al.
Huss, Jr. Albin
Johnson Ivy D.
Klocke Donald J.
Lissy Daria N.
Rahmim Iraj
Garvin Patrick P.
Hobbes Laurence P.
Irzinski E. D.
McKillop Alexander J.
Mobil Oil Corporation
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