Highly ordered nanocomposites via a monomer self-assembly in sit

Compositions – Liquid crystal compositions

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428 1, C09K 1952

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058492151

ABSTRACT:
A method for synthesizing composites with architectural control on the nanometer scale is described. A polymerizable lyotropic liquid-crystalline monomer is used to form an inverse hexagonal phase in the presence of a second polymer precursor solution. The monomer system acts as an organic template, providing the underlying matrix and order of the composite system. Polymerization of the template in the presence of an optional cross-linking agent with retention of the liquid-crystalline order is carried out followed by a second polymerization of the second polymer precursor within the channels of the polymer template to provide an ordered nanocomposite material.

REFERENCES:
Gary et al. "Synthesis of Ordered Nanocomposites Using a Monomer Self-Assembly Approach", Polym. Prepr., Am. Chem. Soc, Mar. 1996.
CA 126: 278043, 1997.

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