Highly heat-resistant positive-working o-quinone diazide contain

Radiation imagery chemistry: process – composition – or product th – Diazo reproduction – process – composition – or product – Composition or product which contains radiation sensitive...

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430193, 430323, 430326, 430313, 430328, G03C 160, G03C 1495

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active

048046124

ABSTRACT:
Although the positive-working photoresist composition comprises a phenolic novolac resin as the film-forming component and a known photosensitizing compound as in conventional compositions, the novolac resin is prepared from a specific mixture of two classes of phenolic compounds including, one, phenol, cresols and/or resorcinol and, the other, one or more of the phenolic compounds having a nucleus-substituting group selected from allyloxy, allyloxymethyl, allyl dimethyl silyl, 2-(allyl dimethyl silyl) ethoxy, cinnamoyl, acryloyl and methacryloyl groups. By virtue of this unique combination to give the phenolic moiety in the novolac resin, the photoresist composition has markedly improved heat resistance as well as stability against plasma in dry etching so that the composition can give a patterned photoresist layer with extreme fineness having high fidelity to the mask pattern.

REFERENCES:
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patent: 4299911 (1981-11-01), Ochi et al.
patent: 4435496 (1984-03-01), Walls et al.
patent: 4439291 (1984-03-01), Irving et al.
patent: 4477553 (1984-10-01), Yamamoto et al.
patent: 4529682 (1985-07-01), Toukhy
Pampalone, T. R., Solid State Technology, pp. 115-120, 6/1984.

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